Wednesday, August 12, 2009

BICARA HARI INI..

salam...

hari ni merupakan hari ketiga persekolahan selepas sekolah ditutup seminggu atas nasihat pihak kesihatan tempatan kerana bimbang penularan jangkitan selsema kerbau pendek ( A H1N1).. pada awanya hanya 8 pelajar disyaki memiliki syimptom2 jangkitan tersebut dan terus meningkat sehingga bilangan yang ramai..

bila kita perkatakan tentang A H1N1, kita tertanya apakah tiada ubat atau vaksin yang sesuai untuk mencegah penularan virus ini..?? sebenarnya memang ada.. tapi itulah gunanya ilmu perlu dimanfaatkan untuk kesinambungan yang lebih baik.. ALLAH telah menjanjikan setipa penyakit ada penawarnya kecuali MATI.. maknanya H1N1 ini masih ada vaksin yang sesuai untuk mencegahnya..

buat masa sekarang apa yang perlu kita lakukan hanyalah menurut saranan kementerian untuk menjaga kebersihan diri dan situasi diri di mana kita berada..

bila kita kembali kepada virus mungkin sebenarnya virus ini dalah sesuatu yang baik bagi hidupan lain.. virus terbina dari protein atau phospholipid dan RNA.. ianya boleh dijadikan sebagai makanan kepada hidupan lain.. akan tetapi penemuan vaksin terkini boleh mngelakkan penularan ini.. kita harus ingat sebenarnya virus merupakn organisma yang terlampau licik.. bila virus dapat mengesan sesuatu dengan pants ia akan mutasi dan berubah maka sebab itu jangkitan virus ini amatlah payah untuk dikawal.. setakat jam 7.00 pm tadi seramai 44 orang telah menjadi korban dripada virus ini.. kecil2 cili maut.. bila besar ntah jadi apa..

td tgahhari kelas kimia buat eksperimen 17.. best jugak tapi memenatkan dan kadang2 membosankan.. apa2 pun semunya dapat dilaksanakan dengan sempurna.. kesannya ujian Pengajian Am K2 tidak jadi.. msa cikgu kadir habis oleh eksprimen.. ngam la 2 time tu kami semua belum sediakan apa2 peralatan buat graf.. kelm kabut gak.. hmmm... sakit gak kepala ni..
p&p macam x berjalan lancar.. sabar jak lah..

p/s : malam ni kena prepare untuk MUET speaking esok pagi.. ada la pulak kena serangan jantung tengok soalan.. hehe2.. nasib grup aku c raqib, dalma n chok.. mesti hadir..


DADIH STRAWBERI



BAHAN-BAHAN:

1 liter susu kotak strawberi
1 cawan air
4 sudu gula
1 sudu serbuk agar-agar
150 ml yogurt



CARA PENYEDIAAN:

1. Mula-mula, masakkan serbuk agar-agar dan air sehingga mendidih.
2. Kemudian, masukkan gula dan kacau sehingga rata dan mendidih
3. Masukkan pula susu kotak strawberi dan kacau rata.
4. Masukkan dalam bekas dan sejukkan
5. Sedia dihidang

p/s : ni aku baru jak makan smalam.. dpt free.. sedap gak.. hehe2.. thanxx to ika..


Tuesday, August 11, 2009

CHEMISTRY- C6 CHEMICAL BONDING

IONIC BONDING


Formation of ionic compounds

Ionic bond:

The electrostatic force of attraction that is strong enough to hold together two unlike charges, namely a cation and an anion is defined as the ionic bond.

In an ionic bond,

  • A metal atom and a non-metal atom are involved.
  • The metal atom loses electron/electrons, and a non-metal atom accepts the electron/electrons.
  • A positively charged ion or cation is formed from a metal atom.
  • A negatively charged ion or anion is formed from a non-metal atom due to the acceptance of electrons from metal atoms.

Formation of sodium chloride

In the formation of sodium chloride,

Na Cl ionic bond formation
As can be seen, a sodium atom has one valence electron, which it needs to lose to attain the neon gas electronic configuration, chlorine has seven valence electrons, it needs one more electron to attain the argon configuration. Sodium atom transfers an electron to the chlorine atom, hence an ionic bond is formed.

The crystal lattice of NaCl reveals that the ions are arranged in a three dimensional pattern, the positive ion alternating with a negative ion.

crystal lattice of NaCl

Crystal lattice of NaCl

The sodium chloride crystal is made up of ions. One sodium ion is surrounded by six chloride ions. One chloride ion is surround by six sodium ions. The crystal is cubic in shape.

Formation of magnesium oxide

magnesium oxide Formation
A magnesium atom has two valence electrons, which it donates to the oxygen atom. Both magnesium and oxygen attain the neon configuration.

Formation of magnesium nitride

The electronic configuration of magnesium is 2,8,2 and that of nitrogen is 2,5.

A magnesium atom needs to lose two electrons, whereas the nitrogen atom needs to gain three electrons to attain the octet.

The chemical formula for magnesium nitride is Mg3N2.

Ion formation takes place as follows:

Each magnesium atom loses two electrons.

Each nitrogen atom gains three electrons.

Mg3N2 formation

Two magnesium atoms donate two electrons to each nitrogen atom while one magnesium atom donates one electron to each of the nitrogen atom. Hence, an ionic bond is formed. Magnesium and nitrogen, thus, attain stability by gaining the octet state.

The conditions necessary for formation of ionic compounds are:

a) It depends primarily on the formation of the cation and anion from neutral atoms.

b) When the difference in electro-negativities of the metal atom and non-metal is large, transfer of electrons take place.

c) A lower ionisation value facilitates easy formation of the cation. For example, the ionisation potential of sodium is 5.1ev, whereas for chlorine it is 13.00ev. Hence, it is easy to remove electrons from a sodium atom.

d) If the electron affinity value is high, it facilitates formation of an anion.

For example, the higher value for chlorine is -3.80ev, so it forms an anion easily.

[Energy released = -3.80ev]

Characteristics of electrovalent compounds

1) Ionic compounds consist of ions and not molecules. For example, sodium chloride is an electrovalent compound consisting of equal number of sodium and chloride ions.

2) Ionic compounds are hard crystalline solids. The crystal of sodium chloride has a definite shape. There is a strong electrostatic force of attraction, which holds the ions together. The ions cannot be easily separated. The crystals are hard and brittle.

3) Ionic compounds have high melting and boiling points. For example, sodium chloride has a high melting point of 1472oF and boiling point of 2575.4oF. Lithium chloride has a melting point of 1122.8oF and boiling point of 2462oF. Potassium chloride has a melting point of 1526oF and boiling point of 2732oF.

As these compounds contain ions held together by strong electrostatic forces, very high amount of energy is required to overcome this force and break the crystal lattice. This explains the high melting point and boiling point of ionic compounds.

4) Electrovalent compounds or ionic compounds are usually soluble in water, but insoluble in organic solvents like ether, acetone, benzene, carbon disulphide and carbon tetrachloride. 'Like dissolves like': Ionic compounds dissolve in polar or ionic solvents.

Water has a high dielectric constant. Water easily breaks the strong electrostatic force of attraction. The water molecule is polar in nature. The positively charged hydrogen atoms surround the anion. The negatively charged OH- (hydroxyl) surround the cation. Hence, the cation is separated from the anion, breaking the crystal lattice. The organic solvents contain non-polar molecules. Therefore, they are unable to break the electrostatic forces of attraction.

5) Ionic compounds conduct electricity when dissolved in water. They also conduct electricity when melted. They do not conduct electricity in the solid state. In the solid state, the ions are held together in fixed positions by the electrostatic forces of attraction. Therefore, the ions are not free. When dissolved in water, the ions are separated. The water molecules break the strong electrostatic force of attraction. This results in the formation of free mobile ions. To conduct electricity, free mobile ions are required. In the molten state too, the ions are separated from each other. The strong electrostatic force of attraction is broken while melting resulting in the formation of free ions.

crystal lattice of sodium chloride
Na Cl bond formation
6) Ionic compounds have a high density. They are generally heavier than water. The oppositely charged ions in an ionic compound are held very closely by strong electrostatic forces of attraction, resulting in the number of ions per unit volume increases. Consequently, increasing in mass per unit volume of the compound.

7) Ionic compounds are involved in ionic reactions. The ionic reactions occur very fast as ions react quickly in solution.

8) Size of the cation involved in bonding is smaller compared to the neutral atom. A cation loses electrons, so there is a reduction in the number of shells. Hence, the size of the ion becomes smaller. On the other hand, in an anion, there is an increase in the number of electrons in a particular shell. This leads to a decrease in the effective nuclear charge. The protons feel a greater attraction towards the electrons, therefore the size is reduced compared to the atom.


COVALENT BONDING


Can we imagine a world without oxygen, nitrogen, water or carbon dioxide? Without any of these there would be no life at all. All the above mentioned compounds are covalent compounds formed by sharing of electrons. Non-metal atoms share the valence electrons and form molecules. These shared pairs of electrons contributed by each of the atoms involved in bonding are located between the nuclei of atoms.
covalent bond formation
covalent bond formation

Covalent bonding may take place between atoms of the same element as in a hydrogen molecule or a chlorine molecule.

It may also take place between atoms of different elements such as:

(i) Hydrogen and chlorine combine to form hydrogen chloride (HCl).

(ii) Carbon and oxygen combine to form carbon dioxide (CO2).

Covalent bonds are formed between non-metal atoms. Each of the atoms involved in bonding contribute one, two, three or more electrons to form the shared pair.

Formation of hydrogen molecule

hydrogen molecule formation
- electron present in K shell of the hydrogen atom

Here the shared pair consists of two electrons, one electron being contributed by each of the hydrogen atoms. This is called a shared pair.

Depending on the number of electron pairs shared between atoms which participate in bonding, covalent bonds are classified as follows:

Align Center


SINGLE COVALENT BONDING


Let us now understand each type of bond in detail.

A single bond consists of one pair of shared electrons. In other words, it is formed by sharing one pair of electrons or two electrons between the atoms, each atom contributing one electron to the bond.

Hydrogen molecule

Hydrogen atom has one electron in its electron shell. It needs one more electron to attain a duplet.

A molecule of hydrogen is formed by the sharing of one pair of electrons between two hydrogen atoms as shown below:
hydrogen molecule structure
The duplet for each atom is complete

The single covalent bond is represented by a short line () between the two atoms.2)">

A chlorine molecule (Cl2)

A chlorine atom is extremely reactive. It cannot exist freely as it does not have a stable electronic configuration. Chlorine does not exist as single atom but as a diatomic molecule. A single covalent bond is formed between two chlorine atoms.

chlorine molecule formation

This bonding can be represented thus,

covalent single bond

Each chlorine atom has an electronic configuration of 2,8,7. It needs one more electron to complete the octet. Each atom gets this electron by sharing one valence electron with another chlorine atom. So, two chlorine atoms share one electron, each to form a chlorine molecule. A strong force of attraction holds these atoms together.

In a molecule of chlorine, each atom has attained the electronic configuration of 2,8,8 resembling argon.

Such a covalent bond involving two atoms of the same element is called homo nuclear covalent bond.

A methane molecule

Methane is a hydrocarbon. It consists of hydrogen and carbon atoms.

Carbon:

Electronic configuration: 2,4 - Carbon atom needs four more electrons to complete its octet.

Hydrogen:

Electronic configuration: 1 - Hydrogen atom needs one more electron to attain the duplet.

As four electrons are needed by the carbon atom, we can infer that there would be four hydrogen atoms involved in bonding wherein, each would share one electron with one electron each of the carbon atom.

Carbon on the other hand, with four electrons forms four shared pairs with four different hydrogen atoms.

This bonding can also be shown as
methane molecule formation
In a methane molecule, the carbon atom attains the octet configuration of neon - 2,8, while the hydrogen atom attains the duplet configuration of helium. In total there are four carbon-hydrogen single bonds. In other words, the molecule has four pairs of shared electrons.

DOUBLE COVALENT BONDING


A double covalent bond consists of two pairs of shared electrons. It is formed by the sharing of two pairs of electrons between two atoms. It is actually a combination of two single bonds. It is represented by putting two short lines between the two atoms [=].

Let us take few examples to understand the double covalent bond in the oxygen molecule.

The oxygen atom cannot exist on its own. It does not have a stable, inert gas electron arrangement. Oxygen gas does not consist of a single atom, but consists of two atoms, which join to form a molecule.

-

O2 atom
O2 atom
electronic configuration = 2,6

oxygen forming covalent bond

Atomic number of oxygen is 8, electronic configuration is 2,6. It needs two more electrons to attain the inert gas configuration. The oxygen atom shares two of its valence electrons with another oxygen atom to form a diatomic oxygen molecule. Each of the oxygen atoms in the covalent molecule consist of eight electrons in the valence shell.

A double covalent bond is stronger than a single covalent bond.

An ethylene molecule (Ethene)

A molecule of ethylene consists of only carbon and hydrogen atoms. It is a hydrocarbon. It has a chemical formula C2H4. What type of covalent bonding is present in this compound?

Carbon:

Electronic configuration is 2,4. It needs four more electrons to complete its octet.

Hydrogen:

Electronic configuration is 1 . It needs one more electron to complete its duplet.

The two carbon atoms share two pairs of electrons to form a double covalent bond. The hydrogen atoms are each linked to the carbon atom by a single bond. In total there are four C-H single bonds and one C=C double bond.

The carbon atom has achieved the electronic configuration of neon and hydrogen, that of helium atom.

Diagrammatically it can be represented as shown below:
C2H4 covalent bond formation

Differences between non-polar and polar covalent compounds

Non polar and polar covalent bondAlign Center


Differences between polar and non-polar covalent bonds

covalent bonds of polar and non polar nature

CHARACTERISTIC OF COVALENT BOND

1) Covalent compounds consist of molecules and not ions. The molecules do not have any electric charge on them. The molecules are held together by weak forces called Van der Waal's forces.

2) Covalent compounds are either gases, volatile liquids or soft solids. As there are weak, Van der Waal's forces between the molecules, they are not held in rigid position. The state depends on the bond energy. If the bond energy is very low, they stay as gases, if it is appreciable they are volatile liquids. If very high, they exist as soft solids.

3) Covalent compounds generally have low melting and boiling points. As Van der Waal's forces are weak, a very small amount of energy is required to break the bond between the molecules corresponding to low melting point and boiling point.

4) Covalent compounds dissolve in organic solvents. As they do not contain ions, solvation does not take place when water is added to the compound. Hence they do not dissolve in water.

5) Covalent compounds are bad conductors of electricity. They do not contain ions in the fused state, nor do ions migrate on application of an electric potential. Hence, there is no conduction of current.

6) Covalent compounds are less dense when compared to water. Very weak Van der Waal's forces hold the molecules together, hence there are large inter molecular spaces. Consequently less number of molecules per unit volume, which means mass per unit volume is also less. Hence they have a low density.

MIXED BONDING

Apart from coordinate covalent compounds, there are some compounds, which contain both ionic and covalent compounds.

For example, sodium hydroxide

In sodium hydroxide, there is an ionic bond between sodium ion Na+ and hydroxide ion, OH-. There is a single covalent bond between oxygen and hydrogen atoms in the hydroxyl ion.

The sodium atom gives away one electron to the hydroxyl ion to form sodium hydroxide.

In hydrogen cyanide HCN, there is an ionic bond between hydrogen ion H+ and cyanide ion CN-. There is a triple covalent bond between carbon and nitrogen in cyanide ion.



P/S : chapter ni senang la ckit nak bawa.. boleh la..





BIOLOGY- MAMMALIAN HEART AND BLOOD CIRCULATION

HEART

Structure

The human heart is a muscular, cone-shaped, hollow organ about the size of a fist (about 12cm in length and 9cm in breadth). The heart is situated behind the sternum, between the lungs in the thoracic cavity. The heart is tilted slightly such that its apex is towards the left side.

illustration of external human heart with their parts
External Heart Anatomy

The major part of the heart is made up of muscles and is called myocardium. The inner lining of the heart is called the endothelium. The heart is covered by a membrane called pericardium. The pericardium encloses the pericardial cavity that houses the heart.

human heart cross sectional view with detailed labels
Internal View of the Heart

The human heart is four-chambered. The upper chambers are called the atria or the auricles and the lower two chambers are called the ventricles. The two atria are separated by the interatrial septum. The two ventricles are separated from each other by the interventricular septum. The ventricles have more muscular walls than the auricles.

The right side of the heart is concerned with deoxygenated blood and the left side of the heart with the oxygenated blood. The right auricle opens into the lower right ventricle. This opening is guarded by auriculo-ventricular valve (auriculo ventricular valve). This valve is called the tricuspid valve as it has three flaps. The flaps of the valves are connected to the walls of the ventricle by tendons called the chorda tendinae.
structure of tricuspid value
Tricuspid Valves The left auricle opens into the lower left ventricle. This opening is guarded by the bicuspid (having two flaps) or the mitral valve. The tricuspid and the bicuspid valves prevent backflow of blood into the auricles from the ventricles when the latter pump the blood into the blood vessels.
location of bicuspid values in the heart
Bicuspid Valves The deoxygenated blood from the different parts of the body are collected by the two major veins called the vena cavae - superior vena cava collecting from the upper body and the inferior vena cava collecting from the lower body. The blood from the vena cavae is poured into the right auricle.

The right ventricle opens to a major artery called the pulmonary artery which takes the deoxygenated blood to the lungs. The junction between the pulmonary artery and the right ventricle is guarded by a semilunar valve. This valve prevents the backflow of blood into the ventricle from the artery.

The left auricle receives oxygenated blood from the left and right pulmonary veins coming from the left and right lung respectively. The left ventricle opens into a major artery called the aorta. The junction between the aorta and the left ventricle is also guarded by semilunar valve that prevents backflow of blood from the aorta into the ventricle.
cross-section of heart, as seen from the front
Section Through Heart
simplified pictorial diagram of the human heart
Simplified Diagram of the Heart Therefore, the right side of the heart is concerned with the deoxygenated blood and the left side of the heart is concerned with the oxygenated blood. Further, the auricles are the receiving chambers and the ventricles are the pumping chambers. When the ventricles pump blood into the blood vessels, the bicuspid and tricuspid valves prevent the backflow into the auricles.
cardiac cycle shows sequence of steps in one heartbeat
Cardiac Cycle

The function of the heart is to pump blood into the blood vessels to ensure that blood reaches all the parts of the body. This is done by the contraction and relaxation of the chambers of the heart. Contraction is called systole and relaxation is called diastole. The pumping action of heart takes place in a rhythmic pattern.

It consists of three stages:
  • Auricular systole or ventricular diastole
  • Auricular diastole or ventricular systole
  • Joint diastole or auricular and ventricular diastole

Auricular Systole or Ventricular Diastole

In the first stage, the auricles or the atria contract with enough pressure to squeeze out all the blood from their cavities into the corresponding ventricles. During this time, the openings from the vena cavae in the right auricle and opening of the pulmonary vein in the left auricles remain closed because of the contraction of the auricles. The semilunar valves guarding the opening of the arteries (aorta and pulmonary artery) are also closed. The auriculo ventricular valves remain open letting blood flow under pressure from the auricles to the ventricles. During this stage, auricles contract and ventricles remain relaxed. This stage is therefore called auricular systole or ventricular diastole.

Auricular Diastole or Ventricular Systole

In the second stage, the auricles relax (diastole). Just as they relax, the flaps of the auriculo ventricular valves snap close. This makes the sound heard as the first heart beat. Once the auriculo ventricular valve is closed, the ventricle contracts (systole). The semilunar valves open as the blood rushes into the arteries from the ventricles.

Joint Diastole or Auricular and Ventricular Diastole

In the last stage, the ventricles start to relax (diastole). This gradually brings down the pressure and at the same time the semilunar valves snap shut to prevent backflow of blood into the heart as the pressure has come down. This produces the second heart beat sound. With the closure of the semilunar valves the ventricles relax further and the auriculo ventricular valves open. Thus, at this stage, both auricles and ventricles are in diastole and hence, the stage is called joint diastole.

The occurrence of the periodic series of events during one heartbeat is called a cardiac cycle. During one heartbeat, there are two heart sounds - 'lub' and 'dub'. 'lub' is the first sound and 'dub' is the second sound.


The control of the heart function is by a set of muscles and is, therefore, called myogenic.

If the heart is removed from a living mammal and placed in a well oxygenated salt solution maintained at 37oC, the heart continues to function though at a slower rate.

location of sino atrial and atrio ventricular nodes in the human heart


CONTROL OF HEART FUNCTION


Position of the Sino-atrial and Atrio-ventricular Nodes

There are certain points in the walls of the heart called the nodes. A node is a collection of muscles. There are two major nodes called the sinoatrial node (Sino-atrial ventricular node) and atrioventricular node (atrio ventricular node). Sino-atrial ventricular node is present at the junction of the vena cavae and the right auricle. It is the initiator of the contraction of heart by making the auricles contract. This is the auricular systole. This impulse is generated and spread by the presence of electrochemical gradient. The impulse is carried to atrio ventricular node that is situated almost at the junction of the auricles and the ventricles. It then transmits it to the other nerves of the heart. The atrio ventricular node is connected to a set of modified cardiac fibres called the 'bundle of His'. From the 'bundle of His' arise various other fine fibres that form a network of fibres running all over the ventricles. These fine fibres are called the Purkinje fibres. Thus, the Sino-atrial ventricular node is called the pacemaker.

In case of failure of the pacemaker, it can be replaced by an artificial battery operated pacemaker.


THE HEART BEAT

The heart beat results in electropotential differences spreading over the heart muscles. These follow a specific pattern. Any change in the pattern indicates an abnormality. The pattern can be recorded using an electrocardiograph. The recorded pattern is called the electrocardiogram (ECG). This is an important diagnostic tool in detecting any defect in the structure and functioning of the heart.



FP180 handheld ECG

The heart rate fast or slow, is controlled by the brain and is therefore called the nervous control The brain has two sites, cardiac accelerator site and the cardiac inhibitory site. The nerves run from these sites in the brain to the different nodes of the heart.

Heart Rate and Pulse Rate

The number of times the heart beats per minute is called heart rate. For a normal adult human it is about 72 times per minute. For infants, it is a higher figure. It also goes up during physical exercise.

The contractions and relaxations that the heart chambers undergo are felt all along the arteries. If a finger is kept at a spot where an artery runs close to the surface, the rhythmic movement can be felt. This is called the pulse. It is found to be much the same as the heart rate. The number of pulses per minute is called the pulse rate.

There is also hormonal control over the heart rate. The common hormones known to increase the heart rate are the adrenaline and thyroxine. Adrenalin is secreted by the adrenal glands and thyroxine by the thyroid gland.


DISEASES AND DISORDERS OF THE CIRCULATORY SYSTEM

Anaemia

The condition in which a number of RBCs per cubic mm being less than normal is called anaemia. It may be due to poor diet or due to excessive bleeding.

Sickle-celled Anaemia

It is a congenital disorder where the red blood cells are sicke-celled. This reduces their oxygen-carrying capacity. It is fatal disorder.

Arterio-sclerosis

It is the hardening of arteries. High levels of blood cholesterol leads to deposition of cholesterol on the walls of the blood vessels. This makes the arterial walls lose their elasticity and result in their hardening.

Hypertension

The arterial blood pressure becomes very high because the stiff walls cannot regulate the pressure changes. This is called hypertension or high blood pressure.

Hypotension or Low Blood Pressure

It is the low arterial blood pressure. It may be due to anaemia or malfunctioning of the heart pump.

Thrombosis

It is the clot formation in the blood vessels which block the heart. Deposition of cholesterol also leads to thrombosis. The narrowing of blood vessels disrupts the secretion of prostacyclin. Prostacyclin prevents the sticking together of platelets. In the absence of this, the coagulated platelets get deposited in the walls and form the clot or the thrombus. This blocks the blood vessel.

P/S: hari ni belajar pasal ni semua.. rasa best sangat2 and dah berinpian nk jadi DOKTOR... teruskan usaha kepada semua..